Annie Chemie P Ltd. India Annie Chemie P Ltd, is a company at Dahej in Gujarat, India. It is a manufacturer exporter of Picric Acid, Picramic acid & Sodium Picramate and oil field shale gas fracking or hydraulic fracturing chemicals and speciality chemicals and it has substantial exports to countries like USA, Canada, UK, Europe, UAE, Nigeria, Algeria, Turkey, Mexico, Brazil, Chile, Argentina, Australia, Kuwait, Dubai etc. We have developed encapsulated guar gel breaker based on coated ammonium persulfate, potassium persulfate, sodium persulfate, potassium peroxymonopersulfate, sodium bromate etc. We also supply other coated or encapsulated products like citric acid, guar crosslinkers other shale gas frac related products like diverting agent, KCl-substitute or clay-stabilizer, corossion inhibitors, scale inhibitor, bio-guard and several speciality chemicals.

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Sodium Picramate SDS of Suppliers Exporters, Manufacturers

Sodium Picramate
CAS Number: 831-52-7 Suppliers Exporters, Manufacturers
Sodium Picramate Manufacturers Exporters

Please visit Main Page of Sodium Picramate Manufacturers.

Sodium Picramate or Sodium 2-amino-4,6-dinitrophenoxide
SDS, Safety Data Sheet
MSDS Sheet
12-May-22

SECTION 1. PRODUCT IDENTIFICATION

Product Name & Other Names: Sodium Picramate or Sodium 2-amino-4,6-dinitrophenoxide.
CAS Number: 831-52-7
EINECS EC Number: 212-603-8
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Supplier: As per the letterhead.

SECTION 2. HAZARDS IDENTIFICATION

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Flammable solids (Category 1), H228
Acute toxicity, oral (Category 4), H302
Acute toxicity, dermal (Category), 4H312
Sensitization, Skin (Category 1), H317
Specific target organ toxicity, repeated exposure (Category 2), H373
Acute toxicity, inhalation (Category 4), H332
Hazardous to the aquatic environment, acute hazard (Category 2), H401

Labeling according to GHS USA & Regulation (EC) No 1272/2008

GHS Label Elements
Flammable
Flammable Solids

GHS Label Elements
Irritant
Irritant

GHS Label Elements
Health Hazard
Health Hazard

Signal Words: Danger

Hazard statements:
H228: Flammable solid.
H302 + H302 + H332: Harmful if swallowed, in contact with skin and if inhaled.
H317: May cause an allergic skin reaction.
H373: May cause damage to organs through prolonged or repeated exposure.

Precautionary statements:
P210: Keep away from heat/sparks/open flames/hot surfaces – No smoking.
P240: Ground/bond container and receiving equipment.
P241: Use explosion-proof electrical/ventilating/light/…/equipment.
P261: Avoid breathing dust/ fume/ gas/ mist/ vapors/ spray.
P262: Do not get in eyes, on skin, or on clothing.
P264 Wash skin thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P330: Rinse mouth.
P301+P312: IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.
P302+P352: IF ON SKIN: Wash with soap and water.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+P351+P338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P337+P313: If eye irritation persists: Get medical advice/ attention.
P370+378: In case of fire: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide for extinction.

SECTION 3. COMPOSITION / INFORMATION ON INGREDIENTS

Product Name & Other Names: Sodium Picramate or Sodium 2-amino-4,6-dinitrophenoxide.
CAS Number: 831-52-7
EINECS EC Number: 212-603-8

SECTION 4. FIRST AID MEASURES

Always seek medical attention after first aid measures are provided.

Eye Contact: Do not allow victim to rub eye (s). Let the eye (s) water naturally for a few minutes. If particle/dust does not dislodge, flush with lukewarm, gently flowing water for 5 minutes or until particle/dust is removed, while holding eyelid (s) open. If irritation persists, obtain medical attention. DO NOT attempt to manually remove anything stuck to the eye.
Skin Contact: Remove contaminated clothing, shoes, and leather goods (e.g., watchbands, belts). Quickly and gently blot or brush away excess chemical. Wash gently and thoroughly with lukewarm gently flowing water and non-abrasive soap for 5 minutes. If irritation persists, repeat flushing. Obtain medical advice. Completely decontaminate clothing, shoes and leather goods before reuse or else discard.
Inhalation: If symptoms are experienced, remove source of contamination or move victim to fresh air. Obtain medical advice.
Ingestion: Never give anything by mouth if victim is rapidly losing consciousness or is unconscious or convulsing. Have victim rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. Have victim drink 2 – 8 oz. (60 – 240 ml) of water.

SECTION 5. FIRE FIGHTING MEASURES

Fire and Explosion Hazards: Flammable Solids.
Extinguishing Media: Use means of extinction appropriate for the surrounding fire conditions such as water spray, carbon dioxide, dry chemical, or foam.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Fire Fighting: Apart from oxides of carbon. toxic fumes of nitrogen oxide may result from combustion. As with any fire, fire fighters should be fully trained and wear full protective clothing including an approved, self-contained breathing apparatus which supplies a positive air pressure within a full-face piece mask. Do not use water directly on material. Do not allow water run-off to enter sewers or watercourses. Use water spray to cool unopened containers. At high temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.

SECTION 6. ACCIDENTAL RELEASE MEASURES

Procedures for Cleanup: Stop release, if possible, to do so safely. Contain spill, isolate hazard area, and deny entry. Sweep up or vacuum. Place contaminated material in suitable, labeled containers for final disposal. Dispose of waste material consistent with the requirements of waste disposal authorities.
Personal Precautions: Gloves and coveralls or other protective clothing are recommended for persons responding to an accidental release. Close-fitting safety goggles may be necessary in some circumstances to prevent eye contact.
Environmental Precautions: This product can pose a threat to the environment. Contamination of soil and water should be prevented. Keep spillage from entering soil, streams, or sewers.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Keep away from sources of ignition - No smoking. Take measures to prevent the build-up of electrostatic charge. Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. generating dust and the release of dust into the workplace. Do not leave the material container open. Store protected from heat, sparks and ignition sources and incompatible materials. Do not store with incompatible materials like oxidizing agents.

SECTION 8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Exposure Limits: This product does not contain any hazardous materials with occupational exposure limits established by the region-specific regulatory bodies.
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures as low as possible. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area.
Personal Respirators (NIOSH Approved): For conditions of use where exposure to dust or mist is apparent and engineering controls are not feasible, a particulate respirator may be worn.
Skin Protection: Wear protective gloves and clean body-covering clothing.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Red-brown solid.
Odor: Not available.
Odor threshold: Not available.
pH: No data found.
Relative density: No data found.
Melting point/freezing point: No data found.
Initial boiling point and boiling range: No data found.
Flash point: No data found.
Auto-ignition temperature: No data found.
Decomposition temperature: No data found.
Upper/lower flammability or explosive limits: No data found.
Vapor pressure: No data found.
Vapor density: No data found.
Evaporation rate: No data found.
Flammability (solid, gas): No data found.
Partition coefficient: n-octanol/water: No data found.
Solubility(ies): Soluble in water.
Viscosity: No data found.
Molecular Formula: C6H4N3O5Na
Molecular Weight: 221.1

SECTION 10. STABILITY AND REACTIVITY

Stability and Reactivity: Stable and not considered reactive under normal temperatures and pressures. Hazardous polymerization or runaway reactions will not occur.
Incompatibilities: Oxidizing agents. Avoid excessive heat.
Hazardous Decomposition Products: High temperature operations will generate carbon oxide fume. Under such conditions, nitrogen dioxide will also be generated and can cause respiratory distress.

SECTION 11. TOXICOLOGICAL INFORMATION

Acute Toxicity (Oral LD50): > 378 mg/kg Mouse
LC50 Inhalation - Rat - 1 h - > 3,900 mg/m3
Carcinogenicity: No component of this product present at levels greater than or equal to 0.1% is identified as possible or confirmed human carcinogen by IARC, ACGIH, OSHA and NTP.
Teratogenic Effects: No data found.
Mutagenic Effects: No data found.
Developmental Toxicity: No data found.
Reproductive Effects: No data found.

SECTION 12. ECOLOGICAL INFORMATION

Ecotoxicity: May cause long lasting harmful effects to aquatic life.
Toxicity to fish
: No data found.
Persistence and Degradability: Readily biodegradable.
Mobility: Likely to be mobile due to water solubility.
Bioaccumulation/ Accumulation: No data found.
Results of PBT and vPvB assessment: No data found.

SECTION 13. DISPOSAL CONSIDERATIONS

Do not wash the material down drain. Put uncontaminated material back into the process if possible. Place contaminated material in suitable, labeled containers for disposal. Dispose of waste material consistent with the requirements of waste disposal authorities.

SECTION 14. TRANSPORT INFORMATION

DOT USA, TDG Canada & ADR/RID Europe:
UN Number: 1349
UN proper shipping name: Flammable solids, organic, n.o.s. (Sodium picramate)
Transport hazard class(es): 4.1; Packaging group: I
IATA/ICAO:
UN Number: 1349
UN proper shipping name: Flammable solids, organic, n.o.s. (Sodium picramate)
Transport hazard class(es): 4.1; Packaging group: I
IMDG/IMO:
UN Number: 1349
UN proper shipping name: Flammable solids, organic, n.o.s. (Sodium picramate)
Transport hazard class(es): 4.1; Packaging group: I.

SECTION 15. REGULATORY INFORMATION

USA Regulations:
SARA 311/312 Hazards: See section 2.
California Prop. 65 Components: This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

SECTION 16 - ADDITIONAL INFORMATION

DISCLAIMER: The information and recommendations set forth herein are presented in good faith and believed correct as of the date hereof. It is compiled from various sources, and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This SDS MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. This shall not constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. In no case shall our company be liable to loss or damages by the product user.

Sodium Picramate Suppliers

Please visit Technical Data Sheet of Sodium Picramate Suppliers.

Picric Acid CAS Number 88-89-1, Picramic acid CAS Number 96-91-3 & Sodium Picramate CAS Number 831-52-7 Supplier Exporter, Manufacturer:

Annie Chemie P Ltd
Mumbai 4000010, INDIA
With Agents and offices in UAE, USA, Europe.

e-mail: info@anniechemie.com

Copyright and Usual Disclaimer is Applicable.
September 30, 2023

Exporters to USA, Canada, UK, Europe, UAE, Nigeria, Algeria, Turkey, Mexico, Brazil, Chile, Argentina, Australia, Dubai etc.

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