Annie Chemie P Ltd. India Annie Chemie P Ltd, is a company at Dahej in Gujarat, India. It is a manufacturer exporter of Hydrated Lime Calcium Hydroxide & Quick Lime Calcium Oxide and oil field shale gas fracking or hydraulic fracturing chemicals and speciality chemicals and it has substantial exports to countries like USA, Canada, UK, Europe, UAE, Nigeria, Algeria, Turkey, Mexico, Brazil, Chile, Argentina, Australia, Kuwait, Dubai etc. We have developed encapsulated guar gel breaker based on coated ammonium persulfate, potassium persulfate, sodium persulfate, potassium peroxymonopersulfate, sodium bromate etc. We also supply other coated or encapsulated products like citric acid, guar crosslinkers other shale gas frac related products like diverting agent, KCl-substitute or clay-stabilizer, corossion inhibitors, scale inhibitor, bio-guard and several speciality chemicals.

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Hydrated Lime Calcium Hydroxide SDS of Suppliers Exporters, Manufacturers

Calcium Hydroxide
CAS Number: 1305-62-0 Hydrated Lime USP BP Ph Eur Reagent FCC Food Grade Suppliers Exporters, Manufacturers
Calcium Hydroxide Manufacturers Exporters

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Calcium Hydroxide SDS, Safety Data Sheet
MSDS Sheet
09-May-22

1. Product Identification

Product Name & Other Names: Calcium hydroxide or Slaked lime or Calcium hydrate or Hydrated lime.
CAS No.: 1305-62-0
EINECS EC Number: 215-137-3
Relevant uses and uses advised against (if any): Industrial Manufacturing.
Suppliers: As per letterhead.

2. Hazards Identification

GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910
Classification according to Regulation (EC) No 1272/2008

Skin corrosion/irritation Category (H315)
Serious eye damage/eye irritation Category 1 (H318)
Acute toxicity, inhalation Category 4 (H332)
Specific target organ toxicity - single exposure, respiratory (Category 3) (H335)
Hazardous to the aquatic environment, acute hazard Category 3 (H402)

Labeling according to GHS & Regulation (EC) No 1272/2008

GHS Label Elements
Corrosive
Corrosive

Signal Words: Danger

Hazard Statements:
H315: Causes skin irritation.
H318: Causes serious eye damage.
H332: Harmful if inhaled.
H335: May cause respiratory irritation.
H402: Harmful to aquatic life.

Precautionary Statements:
P260: Do not breathe dust/fume/gas/mist/vapors/spray.
P264: Wash … thoroughly after handling.
P262: Do not get in eyes, on skin, or on clothing.
P271: Use only outdoors or in a well-ventilated area.
P273: Avoid release to the environment.
P280: Wear protective gloves/protective clothing/eye protection/face protection.
P360: Rinse immediately contaminated clothing and skin with plenty of water before removing clothes.
P362: Take off contaminated clothing and wash before reuse.
P302+352: IF ON SKIN: Wash with soap and water.
P304+340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
P305+351+338: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses if present and easy to do – continue rinsing.
P314: Get Medical advice/attention if you feel unwell.
P332+313: If skin irritation occurs: Get medical advice/attention.
P337+P313 If eye irritation persists: Get medical advice/ attention.

3. Composition/Information on Ingredients

Product Name & Other Names: Calcium hydroxide or Slaked lime or Calcium hydrate or Hydrated lime.
CAS No.: 1305-62-0
EINECS EC Number: 215-137-3

4. First Aid Measures

Always seek medical advice after the first aid treatment.

Inhalation: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician immediately.
Ingestion: DO NOT INDUCE VOMITING. Give copious quantities of water. Never give anything by mouth to an unconscious person. Call a physician immediately.
Skin Contact: In case of contact with Calcium Hydroxide or Slaked Lime , wipe off excess material from skin then immediately flush skin with plenty of water for at least 15 minutes. Remove contaminated clothing and shoes. Wash clothing before reuse. Call a physician immediately.
Eye Contact: Immediately flush eyes with gentle but large stream of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Call a physician immediately.

5. Fire Fighting Measures

Fire: Not considered to be a fire hazard.
Fire Extinguishing Media: Use water spray, alcohol-resistant foam, dry chemical, or carbon dioxide. Use any means suitable for extinguishing surrounding fire.
Special hazards arising from the substance or mixture: Calcium oxide.
Extinguishing Media Not recommended: Avoid using solid water jet as it may scatter the fire.
Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full face piece operated in the pressure demand or other positive pressure mode. At elevated temperatures under fire conditions, it may produce toxic or irritating fumes. Fire-extinguishing work is done from the windward and the suitable fire-extinguishing method according to the surrounding situation is used.

6. Accidental Release Measures

Personal precautions, protective equipment, and emergency procedures: Ventilate area of leak or spill. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.). Do not approach facing the wind.
Environmental precautions: Do not let the product enter drains, soil, or water sources.
Methods and materials used for containment cleanup procedures and Storage:
Contain spilled material. Cover with an inert, non-combustible absorbent material, (e.g., sand, earth, diatomaceous earth, vermiculite). Vacuum or sweep-up and remove to an approved disposal container. Use method that does not generate dust. Do not flush caustic residues to the sewer. Carefully pick up solid with minimum of dusting and collect in metal container with covers with disposal. The trace amount of residue of Calcium Hydroxide or Slaked Lime may be flushed down the drain as per law.

7. Handling and Storage

Precautions for safe handling: Apply according to good manufacturing and industrial hygiene practices. Ensure proper ventilation. In case of insufficient ventilation, wear suitable respiratory equipment. Wash thoroughly after handling. Do not drink, eat, or smoke while handling. Avoid contact with skin, eyes, and clothing. Minimize dust generation. Avoid breathing dust/fumes/gas/mist/vapors/spray. Use individual protective equipment (waterproof boots, suitable protective clothing, safety glasses, etc.).
Conditions for safe storage, including any incompatibilities: Store in cool, dry, and ventilated area away from heat sources and protected from sunlight in tightly closed original container. Keep air contact to a minimum. Store protected from heat, sparks and ignition sources and incompatible materials. Do not store with incompatible materials like strong oxidizing agents and acids. Avoid maleic anhydride, nitro ethane, nitro methane, nitro paraffin, nitro propane, phosphorus.

8. Exposure Controls/Personal Protection

Airborne Exposure Limits: -OSHA Permissible Exposure Limit (PEL):
15 mg/m3 (total dust), 5 mg/m3 (respirable fraction)
-ACGIH Threshold Limit Value (TLV): 5 mg/m3
CALCIUM HYDROXIDE (LIME) WEL (Workplace Exposure Limit) 5 mg/m3
Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits.
Personal Respirators (NIOSH Approved): If the exposure limit is exceeded and engineering controls are not feasible, a full-face piece particulate respirator (NIOSH type N100 filters) may be worn for up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest.
Skin Protection: Wear impervious protective clothing, including boots, gloves, lab coat, apron, or coveralls, as appropriate, to prevent skin contact.
Eye Protection: Use chemical safety goggles and/or full-face shield where dusting or splashing of solutions is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Other Control Measures: Maintain good housekeeping in work area. Handle in accordance with good industrial hygiene and safety practice.

9. Physical and Chemical Properties

Appearance: Calcium Hydroxide or Slaked Lime white crystals or powder.
Odor: Odorless.
Odor threshold: Not applicable.
pH: 12.4 (saturated solution)
Relative density: around 2.24
Boiling Point: Decomposes.
Melting Point: 580C (1076F)
Flash point: No data found.
Auto-ignition temperature: No data found.
Decomposition temperature: No data found.
Upper/lower flammability or explosive limits: No data found.
Vapor pressure: No data found.
Vapor density: No data found.
Evaporation rate: No data found.
Flammability (solid, gas): No data found.
Partition coefficient: n-octanol/water: No data found.
Solubility: 0.185 g/100 cc water @ 0C.
Viscosity: No data found.
Molecular Weight: 74.09
Chemical Formula: Ca(OH)2.

10. Stability and Reactivity

Stability: Stable under ordinary conditions of use and storage. Readily absorbs carbon dioxide from air to form calcium carbonate.
Hazardous Decomposition Products: Decomposition (580C; 1076F) to form Calcium Oxide.
Hazardous Polymerization: Will not occur.
Incompatibilities: Violent reactions with maleic anhydride, nitro ethane, nitro methane, nitro paraffin, nitro propane, phosphorus. As a strongly alkaline material, it is incompatible with acids.

11. Toxicological Information

Oral Rat LD50: 7340 mg/kg; eye rabbit, Standard Draize, 10 mg, severe.
Carcinogenic Effects: Not a reported carcinogen by IARC, NTP, ACGIH, OSHA.
Mutagenic Effects: Investigated as a mutagen.
Teratogenic Effects: No data found.
Developmental Toxicity: No data found.
Reproductive Effects: No data found.

12. Ecological Information

LD50 Oral - Rat - female: > 2.000 mg/kg.
LC50 Inhalation - Rat - male and female - 4 h: > 6,04 mg/l
LD50 Dermal - Rabbit - male and female: > 2.500 mg/kg
Persistence and Degradability: Unlikely to persist.
Mobility: Likely to be mobile.
Bioaccumulation/ Accumulation: Not expected to significantly bio accumulate.
Results of PBT and vPvB assessment: No data found.

13. Disposal Considerations

Although not a listed RCRA hazardous waste, Calcium Hydroxide or Slaked Lime may exhibit one or more characteristics of a hazardous waste and require appropriate analysis to determine specific disposal requirements.

14. Transport Information

DOT USA, TDG Canada & ADR/RID Europe: Not controlled.
IMDG/IMO: Not controlled.
IATA/ICAO: Not controlled.

15. Regulatory Information

USA:
SARA 311/312
: See section 2.

Section 16 - Additional Information

DISCLAIMER: The information and recommendations set forth herein (hereinafter "Information") are presented in good faith and believed correct as of the date hereof. It is compiled from various sources, and it is not necessarily all inclusive nor fully adequate in every circumstance. In addition, these suggestions should not be confused with nor followed in violation of applicable laws, regulations, rules, or insurance requirements applicable. This MSDS sheet is intended only as a guide to the appropriate precautionary handling of the material by a professionally trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose.

Calcium Hydroxide Suppliers

Please visit Technical Data Sheet of Hydrated Lime Calcium Hydroxide USP BP Ph Eur Reagent FCC Food Grade Suppliers.

Hydrated Lime Calcium Hydroxide CAS Number 1305-62-0 & Quick Lime Calcium Oxide CAS Number 1305-78-8 Supplier Exporter, Manufacturer:

Annie Chemie P Ltd
Mumbai 4000010, INDIA
With Agents and offices in UAE, USA, Europe.

e-mail: info@anniechemie.com

Copyright and Usual Disclaimer is Applicable.
September 27, 2023

Exporters to USA, Canada, UK, Europe, UAE, Nigeria, Algeria, Turkey, Mexico, Brazil, Chile, Argentina, Australia, Dubai etc.

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